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Bahnhof vs. Station

The German words Bahnhof and Station both relate to locations where things stop or depart, but they have distinct applications. A Bahnhof is specifically a physical railway station, usually featuring associated buildings and infrastructure for trains. On the other hand, Station is a much broader term that can mean a smaller public transport stop, a specialized scientific or space facility, a specific ward in a hospital, or a figurative stage in a journey.

Bahnhof

A1
The word Bahnhof translates to a train station or railway station. It is heavily associated with rail transport and usually implies a permanent building or an official infrastructure hub where regional, national, or international trains operate. It can also form compound words for major hubs, such as a main train station or a major bus terminal.
Der Zug erreicht den Bahnhof in etwa zehn Minuten.
(The train will reach the railway station in about ten minutes.)
Wir wollen uns am neuen Zentralen Omnibusbahnhof treffen.
(We want to meet at the new central bus terminal.)
Dieser alte Bahnhof wird nicht mehr von großen Zügen angefahren.
(This old train station is no longer served by large trains.)
Meine Schwester holt mich heute Nachmittag vom Hauptbahnhof ab.
(My sister is picking me up from the main station this afternoon.)
Vor dem Bahnhof warten viele Taxis auf neue Fahrgäste.
(Many taxis are waiting for new passengers in front of the train station.)

Station

A2
The word Station is a highly versatile term. In public transport, it usually refers to a smaller stop without an extensive main building, such as a subway stop or tram stop. Outside of transport, Station refers to a scientific or astronomical outpost, a specific ward or department within a hospital, or an individual phase or stop along a long journey or process.
Ich muss an der nächsten Station der U-Bahn aussteigen.
(I have to get off at the next subway stop.)
Der Patient wurde gestern auf eine andere Station verlegt.
(The patient was moved to a different hospital ward yesterday.)
Die internationale Raumstation kann man manchmal am Nachthimmel sehen.
(You can sometimes see the international space station in the night sky.)
Rom war die letzte Station auf unserer langen Rundreise durch Europa.
(Rome was the final stop on our long tour through Europe.)
Die Forscher bauen eine neue Station am Südpol auf.
(The researchers are building a new facility at the South Pole.)
Dieser kleine Zug hält an jeder einzelnen Station auf der Strecke.
(This small train stops at every single stop along the route.)

Summary

In summary, use Bahnhof when talking about a proper train station or a major transit terminal with dedicated buildings and infrastructure. Choose Station for a much wider variety of meanings, including a smaller transit stop like those on the subway, specialized outposts, hospital wards, or stages of a journey. While a Bahnhof represents a major transport node, a Station represents a point on a path or a dedicated unit within a larger system.